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  4. /Zeeman Effect Calculator

Zeeman Effect Calculator

Calculator

Results

Energy Shift

0.000058

eV

Energy Shift

9.274000e-24

J

Frequency Shift

13,996,377,905.2219

Hz

Wavelength Shift

-16,185,458.064192

nm

Results

Energy Shift

0.000058

eV

Energy Shift

9.274000e-24

J

Frequency Shift

13,996,377,905.2219

Hz

Wavelength Shift

-16,185,458.064192

nm

The Zeeman Effect Calculator computes the energy splitting and spectral line shift of atomic transitions in an external magnetic field. The Zeeman effect, discovered by Pieter Zeeman in 1896 (Nobel Prize 1902 shared with Lorentz), is the splitting of atomic spectral lines into multiple components when the atom is placed in a magnetic field.

In the normal Zeeman effect (applicable when spin effects are negligible or cancel), a single spectral line splits into three components with equal spacing. The energy shift of each component depends on the magnetic quantum number m_l and the magnetic field strength B: delta_E = m_l * mu_B * B, where mu_B = 9.274 x 10^-24 J/T is the Bohr magneton.

The Bohr magneton represents the fundamental magnetic moment of an electron due to its orbital motion. The three components (m_l = -1, 0, +1 for an l=1 to l=0 transition) are separated by exactly one cyclotron frequency spacing nu_L = eB/(4*pi*m_e), known as the Larmor frequency.

The anomalous Zeeman effect, which shows more than three components, arises from electron spin and requires the full quantum mechanical treatment with the Lande g-factor. This calculator implements the normal (orbital) Zeeman effect for a given magnetic quantum number.

The Zeeman effect has important applications in solar and stellar physics (measuring magnetic fields in sunspots and stellar atmospheres), plasma diagnostics, magnetic resonance spectroscopy, and laser cooling and trapping of atoms (the Zeeman slower uses a spatially varying magnetic field to compensate for Doppler shifts as atoms decelerate).

Visual Analysis

How It Works

The energy shift is delta_E = m_l * mu_B * B, where mu_B = 9.274 x 10^-24 J/T (Bohr magneton), m_l is the magnetic quantum number (integer), and B is the field in Tesla. The frequency shift is delta_E / h and the wavelength shift is approximately -lambda^2 * delta_E / (h*c).

Understanding Your Results

At 1 T the energy splitting per m_l unit is ~5.79 x 10^-5 eV or ~14 GHz. In solar sunspots (B ~ 0.3 T) the Zeeman splitting of iron lines is measurable from Earth. At laboratory fields of 1-10 T the frequency splitting is in the microwave-to-THz range, easily resolved with modern spectrometers.

Worked Examples

Sodium D-line in 1 T Field

Inputs

B tesla1
m l1
lambda nm589

Results

energy shift eV0.0000579
energy shift J9.274e-24
freq shift Hz14000000000
wavelength shift nm-0.0000814

The sodium D-line at 589 nm shifts by about 0.08 pm per unit of m_l in a 1 T field, giving the characteristic triplet pattern of the normal Zeeman effect.

Sunspot Field (0.3 T) on 630 nm Fe Line

Inputs

B tesla0.3
m l1
lambda nm630

Results

energy shift eV0.0000174
energy shift J2.78e-24
freq shift Hz4200000000
wavelength shift nm-0.0000277

Solar physicists measure magnetic fields in sunspots (typically 0.2-0.4 T) by measuring the Zeeman splitting of iron spectral lines at 630 nm.

Frequently Asked Questions

The Bohr magneton mu_B = e*hbar/(2*m_e) = 9.274 x 10^-24 J/T is the fundamental unit of magnetic dipole moment for an electron. It represents the magnetic moment due to one unit of orbital angular momentum.

The normal Zeeman effect shows exactly three lines and arises in states where spin effects cancel (singlet states). The anomalous Zeeman effect shows more lines due to electron spin, requiring the full g-factor treatment.

Solar spectropolarimetry measures the circular and linear polarization of Zeeman-split spectral lines. The splitting directly gives the field strength while polarization gives the field direction.

The Larmor frequency nu_L = eB/(4*pi*m_e) = mu_B*B/h is the classical precession frequency of a magnetic moment in field B. Normal Zeeman components are separated by exactly the Larmor frequency.

At very high magnetic fields where the Zeeman splitting exceeds the spin-orbit coupling energy, the spectrum reverts to a simpler pattern called the Paschen-Back effect, where L and S decouple from J.

Not easily for optical lines. However, microwave and radio Zeeman effects (21 cm hydrogen line splitting) can be observed with radio telescopes and are used to map interstellar magnetic fields.

A device used in laser cooling experiments where a spatially varying magnetic field creates position-dependent Zeeman shifts that compensate for the Doppler shift as an atom slows down, keeping it in resonance with the cooling laser.

MRI uses the nuclear Zeeman effect: proton spin states split in a strong magnetic field and radio frequency pulses drive transitions between them. The resonance frequency (Larmor frequency of protons) directly gives the local field strength.

For an electron in state with orbital quantum number l, m_l takes integer values from -l to +l (total 2l+1 values). A p electron (l=1) has m_l = -1, 0, +1 giving three Zeeman sublevels.

Yes. Zeeman lasers use a magnetic field applied to the gain medium to produce two circularly polarized modes at slightly different frequencies, useful for precision measurement of magnetic fields and rotation sensors.

Sources & Methodology

Zeeman, P. (1897). The Effect of Magnetisation on the Nature of Light Emitted by a Substance. Nature, 55, 347. Foot, C. J. Atomic Physics. Oxford University Press. Demtroder, W. Laser Spectroscopy.
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