-1.511111
eV
-3.4
eV
-1.888889
eV
1.888889
eV
3.026333642e-19
J
656.387
nm
456,731,301,282,706.75
Hz
15,234.916
cm^-1
-1
-1.511111
eV
-3.4
eV
-1.888889
eV
1.888889
eV
3.026333642e-19
J
656.387
nm
456,731,301,282,706.75
Hz
15,234.916
cm^-1
-1
The Hydrogen Energy Levels Calculator computes the quantized energy levels of the hydrogen atom and the properties of photons emitted or absorbed during transitions between levels. The hydrogen atom, with its single proton and single electron, is the simplest atomic system and the cornerstone of atomic physics.
Niels Bohr's 1913 model introduced the revolutionary idea that electrons occupy discrete energy levels given by $$E_n = -\frac{13.6 \text{ eV}}{n^2}$$ where n = 1, 2, 3, ... is the principal quantum number. The ground state (n = 1) has E₁ = –13.6 eV, meaning 13.6 eV of energy is needed to ionize the atom. As n increases, the energy levels converge toward zero (the ionization threshold), with ever-decreasing spacing.
When an electron transitions from a higher level nᵢ to a lower level n_f, it emits a photon with energy equal to the difference: $$\Delta E = 13.6 \left(\frac{1}{n_f^2} - \frac{1}{n_i^2}\right) \text{ eV}$$ The photon wavelength follows from λ = hc/ΔE. Conversely, absorption of a photon with exactly this energy promotes the electron upward.
The spectral series of hydrogen are named after their discoverers: the Lyman series (transitions to n = 1, ultraviolet), Balmer series (to n = 2, visible), Paschen series (to n = 3, infrared), and Brackett and Pfund series (to n = 4 and 5, far infrared). The Balmer series is especially important historically because its visible lines (H-alpha at 656 nm, H-beta at 486 nm, etc.) were the first atomic spectral lines to be systematically studied.
Although Bohr's model has been superseded by the full quantum mechanical treatment (Schrödinger equation for hydrogen), the energy level formula remains exactly correct for hydrogen. The calculator is essential for spectroscopy, astrophysics (stellar classification relies on hydrogen lines), laser physics, and quantum chemistry courses.
Beyond hydrogen, the formula generalizes to hydrogen-like ions (He⁺, Li²⁺, etc.) by multiplying 13.6 eV by Z², where Z is the nuclear charge. This extension makes the model useful for understanding the spectra of highly ionized atoms in stellar atmospheres and fusion plasmas.
The calculator uses the Bohr model energy formula and photon relations:
Energy of Level n:
$$E_n = -\frac{13.6 \text{ eV}}{n^2}$$
The negative sign indicates a bound state (energy must be added to free the electron).
Transition Energy:
$$|\Delta E| = |E_i - E_f| = 13.6 \left|\frac{1}{n_f^2} - \frac{1}{n_i^2}\right| \text{ eV}$$
Photon Wavelength:
$$\lambda = \frac{hc}{|\Delta E|}$$
where h = 6.626 × 10⁻³⁴ J·s and c = 3 × 10⁸ m/s.
Photon Frequency:
$$f = \frac{|\Delta E|}{h}$$
If nᵢ > n_f, the transition is emission (photon released). If nᵢ < n_f, it is absorption (photon absorbed).
The energy values are negative, reflecting bound states. A transition from a higher to lower level (emission) releases a photon whose wavelength you can use to identify the spectral line. The Balmer series transitions (to n = 2) produce visible light: H-alpha (n=3→2, 656 nm, red), H-beta (n=4→2, 486 nm, blue-green), H-gamma (n=5→2, 434 nm, violet). Lyman series photons (to n = 1) are ultraviolet, while Paschen and higher series are infrared. The photon type output indicates whether the process is emission (1) or absorption (0).
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The H-alpha transition emits a photon at 656 nm (red light). This is the most prominent visible line in the hydrogen spectrum and is widely used in solar and stellar observations.
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The Lyman-alpha line at 121.6 nm is the strongest UV emission line of hydrogen. It is used in cosmology to detect distant galaxies through Lyman-alpha emission.
The negative sign means the electron is bound to the proton. The zero of energy is defined as the ionization threshold (electron at rest, infinitely far from the proton). Bound states have less energy than a free electron, hence negative values. The ground state at –13.6 eV means you must supply 13.6 eV to completely remove the electron.
The Rydberg formula 1/λ = R₁(1/n_f² – 1/n_i²) predicts the wavelength of spectral lines, where R₁ = 1.097 × 10⁷ m⁻¹ is the Rydberg constant. It is mathematically equivalent to using ΔE = 13.6|1/n_f² – 1/n_i²| eV and λ = hc/ΔE. This formula was discovered empirically before quantum mechanics explained it.
Each series corresponds to transitions ending at a specific level: Lyman (n_f = 1, UV), Balmer (n_f = 2, visible), Paschen (n_f = 3, near-IR), Brackett (n_f = 4, IR), and Pfund (n_f = 5, far-IR). The Balmer series is the most historically significant because its lines fall in the visible spectrum and were the first to be studied systematically.
The exact formula E_n = –13.6/n² eV applies only to hydrogen. For hydrogen-like ions (one electron orbiting a nucleus with charge Z), the formula becomes E_n = –13.6·Z²/n² eV. For multi-electron atoms, electron-electron repulsion breaks the simple 1/n² pattern, and more sophisticated quantum mechanical methods are needed.
The ionization energy is the energy required to remove the electron from the ground state (n = 1) to infinity (n = ∞). Since E₁ = –13.6 eV and E∞ = 0, the ionization energy is 13.6 eV (or 1312 kJ/mol). This is one of the most precisely measured quantities in physics.
The energy levels follow E_n = –13.6/n², so the spacing between adjacent levels is ΔE ≈ 2·13.6/n³ for large n. As n increases, the spacing shrinks as 1/n³, and the levels converge toward zero. This explains why spectral series have a series limit — a shortest wavelength beyond which the lines merge into a continuum corresponding to ionization.
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