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  1. Home
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  3. /Physical Chemistry Calculators - Quantum Chemistry
  4. /De Broglie Wavelength Calculator

De Broglie Wavelength Calculator

Calculator

Results

Wavelength from Mass & Velocity

7.274202e-10

m

Wavelength from Momentum

6.626070e-10

m

Wavelength from Kinetic Energy & Mass

1.226452e-10

m

Momentum from Mass & Velocity

9.109000e-25

kg·m/s

Velocity From Energy

5.931094e+6

m/s

Kinetic Energy

1.602177e-17

J

Results

Wavelength from Mass & Velocity

7.274202e-10

m

Wavelength from Momentum

6.626070e-10

m

Wavelength from Kinetic Energy & Mass

1.226452e-10

m

Momentum from Mass & Velocity

9.109000e-25

kg·m/s

Velocity From Energy

5.931094e+6

m/s

Kinetic Energy

1.602177e-17

J

The de Broglie wavelength is one of the most revolutionary concepts in quantum mechanics, establishing that all matter exhibits wave-particle duality. Proposed by Louis de Broglie in his 1924 doctoral thesis, this hypothesis extended the wave-particle duality already known for photons to all particles with mass. The De Broglie Wavelength Calculator computes the quantum mechanical wavelength associated with a particle given its mass and velocity, momentum, or kinetic energy. For electrons, the de Broglie wavelength is on the order of picometers to nanometers, comparable to atomic dimensions, which is why electron diffraction can probe crystal structures. For macroscopic objects, the wavelength is extraordinarily small and undetectable. This concept underpins electron microscopy, neutron diffraction, quantum tunneling, and the entire framework of wave mechanics that Schrödinger later formalized.

Visual Analysis

How It Works

The de Broglie relation connects a particle's wavelength to its momentum:

$$\lambda = \frac{h}{p} = \frac{h}{mv}$$

where h = 6.626 × 10⁻³⁴ J·s is Planck's constant, m is the particle mass, and v is its velocity.

When kinetic energy (KE) is known instead of velocity:

$$KE = \frac{p^2}{2m} \implies p = \sqrt{2mKE}$$

$$\lambda = \frac{h}{\sqrt{2mKE}}$$

For electrons accelerated through a potential difference V (in volts):

$$\lambda = \frac{h}{\sqrt{2m_e eV}} = \frac{1.226}{\sqrt{V}} \text{ nm}$$

This is the basis for electron microscopy—higher accelerating voltages produce shorter wavelengths and better resolution. The de Broglie hypothesis was experimentally confirmed by Davisson and Germer (1927) through electron diffraction from nickel crystals.

Understanding Your Results

The de Broglie wavelength determines the scale at which quantum effects become important. When λ is comparable to the system size (atomic spacings, slit widths), wave phenomena like diffraction and interference appear. For an electron at 100 eV, λ ≈ 0.123 nm—comparable to atomic spacings in crystals, enabling diffraction experiments. For a 1 kg ball moving at 1 m/s, λ ≈ 6.6 × 10⁻³⁴ m—far too small to detect. The transition between quantum and classical behavior occurs roughly when de Broglie wavelength becomes much smaller than the relevant length scale. Note: this non-relativistic formula is valid when v << c. For particles approaching the speed of light, relativistic momentum must be used.

Worked Examples

Electron at 1×10⁶ m/s

Inputs

calcModemv
mass9.109e-31
velocity1000000

Results

wavelengthM7.274e-10
wavelengthNm0.7274
wavelengthPm727.4
momentumOut9.109e-25

An electron moving at 10⁶ m/s has λ ≈ 0.73 nm, comparable to X-ray wavelengths and suitable for probing crystal structures.

100 eV Electron (Kinetic Energy)

Inputs

calcModeke
mass9.109e-31
velocity1000000
momentum1e-24
kineticEnergy100

Results

wavelengthM1.226e-10
wavelengthNm0.1226
wavelengthPm122.6
momentumOut5.403e-24

A 100 eV electron has λ ≈ 0.123 nm = 1.23 Å, perfect for electron diffraction studies of atomic-scale structures.

Frequently Asked Questions

It is the wavelength associated with any moving particle, given by λ = h/p. It demonstrates that matter has both particle and wave properties—a cornerstone of quantum mechanics proposed by Louis de Broglie in 1924.

Yes, but it is immeasurably small. A 1 kg ball at 1 m/s has λ ≈ 6.6 × 10⁻³⁴ m—about 10¹⁹ times smaller than a proton. Quantum wave effects are completely undetectable at macroscopic scales.

In 1927, Davisson and Germer observed electron diffraction from a nickel crystal, and independently G.P. Thomson showed electron diffraction through thin metal foils. The measured diffraction patterns matched predictions from de Broglie's wavelength formula.

Since p = √(2mKE), the wavelength is λ = h/√(2mKE). Wavelength decreases with increasing kinetic energy—faster particles have shorter wavelengths and can probe finer structures.

Electron microscopes accelerate electrons to high energies, giving them very short de Broglie wavelengths (0.001–0.1 nm). This allows resolution far beyond the ~200 nm limit of optical microscopes, enabling visualization of individual atoms.

Thermal neutrons at room temperature (~0.025 eV) have λ ≈ 0.18 nm, comparable to atomic spacings. This makes neutron diffraction ideal for studying crystal structures, especially for locating light atoms like hydrogen.

Photons have zero rest mass, so the formula λ = h/(mv) doesn't directly apply. Instead, use the photon momentum relation p = h/λ = E/c. The de Broglie relation λ = h/p remains valid with relativistic momentum.

When particle velocity exceeds about 10% of c (3 × 10⁷ m/s), use relativistic momentum: p = γmv where γ = 1/√(1−v²/c²). For electrons above ~10 keV, relativistic effects become significant.

It is λ_th = h/√(2πmkT), representing the average wavelength of particles at temperature T. When λ_th approaches the interparticle spacing, quantum statistics (Bose-Einstein or Fermi-Dirac) become important.

A well-defined wavelength implies well-defined momentum (p = h/λ) but complete uncertainty in position (the wave extends everywhere). The uncertainty principle Δx·Δp ≥ ħ/2 quantifies this tradeoff between position and momentum knowledge.

Sources & Methodology

de Broglie L. Recherches sur la théorie des quanta. PhD thesis, University of Paris, 1924. Griffiths DJ. Introduction to Quantum Mechanics, 3rd ed. Cambridge University Press, 2018. Davisson C, Germer LH. Diffraction of Electrons by a Crystal of Nickel. Physical Review, 30(6), 705–740, 1927. Atkins P, de Paula J. Atkins' Physical Chemistry, 11th ed. Oxford University Press, 2018.
R

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